Cooperative 1D Triazole-Based Spin Crossover FeII Material With Exceptional Mechanical Resilience

نویسندگان
چکیده

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Cooperative Triazole Based Spin Crossover FeII Coordination Polymers

Narsimhulu Pittala1, Smail Triki1, Franck Thétiot1, Kamel Boukheddaden2, Guillaume Chastanet3, Mathieu Marchivie3 1Department Of Chemistry, UMR CNRS 6521, Université De Bretagne Occidentale (UBO), Brest, France, 2Groupe d\'étude de la matière condensée (GEMaC), Université de Versailles Saint-Quentin, Versailles, France, 3CNRS, Université Bordeaux, ICMCB, UPR 9048, Bordeaux, France E-mail: narsi...

متن کامل

Spin crossover-macromolecule composite nano film material.

A kind of spin crossover-macromolecule polymer composite material, [Fe(NH(2)trz)(3)(ClO(4))(2)]-PVP (NH(2)trz is 4-amino-1,2,4-triazole and PVP is polyvinylpyrrolidone), appears as homogeneous film with a regular structure in nano-scale and shows the spin crossover (SC) phenomenon.

متن کامل

1D to 3D Crossover of a Spin-Imbalanced Fermi Gas.

We have characterized the one-dimensional (1D) to three-dimensional (3D) crossover of a two-component spin-imbalanced Fermi gas of ^{6}Li atoms in a 2D optical lattice by varying the lattice tunneling and the interactions. The gas phase separates, and we detect the phase boundaries using in situ imaging of the inhomogeneous density profiles. The locations of the phases are inverted in 1D as com...

متن کامل

High-temperature photo-induced switching and pressure-induced transition in a cooperative molecular spin-crossover material.

The thermal and photo-induced switching properties of the recently published molecular spin crossover complex [Fe(H4L)2](ClO4)2·H2O·2(CH3)2CO () have been investigated in detail through Raman spectroscopy. Magnetometric and single crystal X-ray diffraction kinetic studies within the hysteresis loop have proven its metastable character, which allowed establishing the shape of the true, quasi-sta...

متن کامل

Spin crossover in polymeric and heterometallic FeII species containing polytopic dipyridylamino-substituted-triazine ligands.

We report the synthesis and characterisation of the new polytopic ligands, ddta (N,N-di(pyridin-2-yl)-4,6-di(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)-1,3,5-triazin-2-amine) and tptd (N(2),N(2),N(4),N(4)-tetra(pyridin-2-yl)-6-(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)-1,3,5-triazine-2,4-diamine). Each contains N-donor dipyridylamino binding sites as well as separate and distinct mono-...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Chemistry of Materials

سال: 2016

ISSN: 0897-4756,1520-5002

DOI: 10.1021/acs.chemmater.6b04118